Comment by alnwlsn

The form factor I'd like to see standardized would be a flat pack like the Nokia phone battery.

Not saying the cylinder doesn't have it's place, but so many of my devices would like a flat pack.

If that happened, it'd have the added benefit of being able to standardized a bms protocol for the packs. Hard to have control pins with a cylinder.

And if you were super clever, you'd make those packs stackable so they could be charged and discharged together.

I just worry that the voltage of these is a bit too high, if the device takes 3 or 4 in series. They tend to be around 1.8 volts per cell, significantly higher than a fresh alkaline AA at around 1.6 volts, and even after half the energy is discharged, if the device is off for a long while, the initial voltage for next turn-on creeps all the way back up.

(The price doesn't bother me ... it's worth the much lower chance of leaking than alkaline, if you leave it in a remote or gadget for years. But I've come to think that rechargeable NiMH like eneloops are a better idea due to the voltage.)

No, there's basically no reason you'd ever want an alkaline battery except cost. For your use case of long-term storage or a rarely used flashlight (e.g. in a car emergency kit), you'd want a Li/FeS2 as the parent poster recommended, also called just a "Lithium" primary (i.e. non-rechargable) cell. They have a longer shelf life, don't leak, hold more energy, can provide a higher discharge current, work over a wider temperature range, and have safety characteristics very similar to alkaline.

> You're probably better off going with old-fashioned alkaline batteries.

Never. They will leak and die. Alkaline cells always end up leaking and dying in my experience, given enough time.

In fact, I do the reverse: If it's something I think will sit for a long time, I make sure to put a rechargeable battery in it. That way, worst case, it's dead—but it won't be destroyed by a leak.

Alkaline has a tendency to leak electrolyte when stored in devices long-term, especially if used intermittently, even more so if the loads are at the upper end of what alkaline can handle as they are in many modern flashlights. The electrolyte is corrosive and often results in a broken device, which is exactly what you don't want in an emergency.

Li-ion's self-discharge is pretty low for a bare unprotected cell, and a flashlight with a mechanical switch consumes no power when off. One must take care to avoid short circuits when handling such a cell, but modern Li-ion flashlights have over-discharge protection, so that's the main safety concern with a single-cell design.

I've taken the approach of electrical-taping my USB-chargeable 14500s each to a dummy-battery, since the things I put them in have 2 adjacent slots for series AAs. The voltage is still high (3.somethingV instead of 3V) but they seem to work.

I swab the corroded contacts with white vinegar from the kitchen. It turns the white gunk into a foamy blob, and I assume it etches off enough of the corrosion to restore conductivity. I wipe the foamy part with the dry side of the cotton swab, and the device usually works again.

I started doing this as a kid, reasoning that the white gunk looked like baking soda, which is fun to combine with vinegar, so let's see what happens. I just looked it up, and it appears that the process is legitimate and safe. The vinegar turns potassium carbonate into potassium acetate, also producing carbon dioxide.

Pish, what's the worst that could happen when rusted steel and aluminum are kept in a sparky environment?