Comment by ben_w

I don't know where you get these ideas from, but they're very very wrong.

You can already buy PV for sunlight with higher efficiency than 27%. Heck, even with a single band gap the limit for *sunlight* with all the problems I've just stated (because a broad spectrum will waste energy and the sun's spectrum is very broad) still gets you to the 33% Shockley–Queisser limit for one junction on the solar spectrum: https://en.wikipedia.org/wiki/Shockley–Queisser_limit

But for monochromatic light, tuned to the band gap, stuff people have already built is several times better than that, and the theoretical limit is basically how finely you can tune the laser bandwidth and how precisely you can control impurities that broaden the band gap.

Here's one designed for monochromatic laser use, that was actually built, with results published in early 2019, with 70% where they recon doing it better would get to 80%: https://krichlab.ca/wp-content/uploads/2019/02/Xia18-PVSC.pd...

As with all quantum systems, which is what both PV and lasers are, the ultimate efficiency of a tuned laser-and-band-gap pair is as good as your engineering, hence ~99.9% (on the cell side) if you control absolutely all parts of it properly.